Abstract
The dehydration processes of heteropoly hexamolybdate and dodecatungstate complexes of gallium were investigated. The kinetics of dehydration were studied in a flow reactor, the obtained activation energy values being 50–107 kJ/mol, and the pre-exponential factor 104−1013s−1. The nature of the external cation does not influence the dehydration kinetics essentially. The activation energy and pre-exponential factor values increase on transition from the high-hydrated tungstates to the low-hydrated molybdates.
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