Abstract
Experimental mass spectrometric data obtained by the Knudsen effusion mass spectrometry are used to analyze principal tendencies in the formation of complex oxides contained in the gas phase over compounds and melts in the CaO–MgO–Al2O3–TiO2–SiO2 system. Dependences are derived for concentrations of the complex molecular species in the gas phase at the vaporization of mullite Al6Si2O13, wollastonite CaSiO3, spinel MgAl2O4, perovskite CaTiO3, and the Al2O3–SiO2 and CaO–SiO2 binary boundary systems on temperature, melt composition, and oxygen partial pressure.
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