Abstract
Cerleaside A is a glycoside isolated in small amounts from the leaves of Cerbera odollam Gaertn. The aglycone part is a rearranged steroid substitued at C17 by a γ-lactone and at C3 by a sugar, L-thevetose. One water molecule, which is distributed on two sites with an occupancy factor of 0.5, is in a cavity delimited by the sugar and lactone groups to which it is hydrogen bonded
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