Study of an EE mechanism using double potential step techniques

Abstract

An analytical solution corresponding to the double potential step problem for a reversible EE mechanism is presented. This solution is applicable to any double pulse technique without restrictions on the duration of the first and second potential steps and is valid when several species are initially present in the solution. The influence of the duration of the two pulses on the characteristic of the current–potential curves on differential and reverse double pulse techniques in static and dynamic electrodes is also discussed.