Abstract
A unique heteronuclear tartaric coordination complex [C12H20Cu2KNaO24] was synthesized by the interaction of potassium‐sodium tartarate with CuCl2. Its X‐ray crystal structure shows that the new coordination complex belongs to a monoclinic system, P2(1) space group. The crystallographic data are: a=7.6429(15)Å, b=20.753(4) Å, c=8.1058(16)Å, α=90°, β=112.06(3)°, γ=90°. In this complex, two Cu(II) ions that are in different coordination environments and 2 tartarate ligands exist in cyclic forms. These cyclic structures are connected by Na(I)–K(I) ion pairs and then form the complicated crystal structure through the hydrogen‐bond network.
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