Studies on Electrical, Thermal and Corrosion Behaviour of Cashew Tree Gum Grafted Poly(Acrylamide)

Abstract

The present work aimed to study the thermal transitions, electrical properties and corrosion behaviour of cashew tree gum (CTG), poly (acrylamide) (PAM) and cashew tree gum grafted poly (acrylamide) (CTG-g-PAM) copolymer. Various amounts of acrylamide monomer were grafted onto cashew gum using a radical polymerization method. The formation of graft copolymer was analysed by FTIR, UV, SEM, DSC and electrical conductivity measurements. The FTIR and UV spectrum infers the occurrence of strong intermolecular interaction between cashew gum and poly (acrylamide). SEM photographs revealed that the acrylamide unit was well inserted into the cashew gum segments. The DSC analysis showed a significant decrease in glass transition temperature with an increase in amount of acrylamide chains. CTG shows higher AC conductivity than PAM and the conductivity of graft copolymer increases with the concentration of acrylamide up to certain concentration of monomer and thereafter the value decreases. The dielectric properties such as dielectric constant and dielectric loss tangent values of PAM was lower than CTG and the dielectric values also shows a similar trend as AC conductivity. CTG, PAM and its graft copolymer with various amount of poly (acrylamide) have been investigated as a corrosion inhibition for mild steel in hydrochloric acid. The inhibition efficiency increased with increase in concentration of PAM in the graft copolymer. PAM was found to have the high inhibition efficiency than CTG, due to the difference in their molecular structures. The corrosion rate of all the samples enhanced with the raise in temperature whereas the inhibition efficiency deceases.