Abstract
The photoelectron (PE) spectra of 14 molecules which are fragments of buspirone analogues have been recorded. The interpretation of bands between 7 and 11 eV has been carried out by means of a fragment-to-fragment approach and MNDO calculations. It is shown that a number of methylsubstituted derivatives have non-planar geometries. The corresponding torsion angles are evaluated by means of MNDO calculations. The PE spectra of these compounds are analysed up to 10 eV.
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