Abstract
The single-crystal polarised electronic spectra, e.s.r., and magnetic anisotropy of tetra-(6-aminohexanoic acid)copper(II) diperchlorate are reported. These properties are interpreted by use of a point-charge crystal-field model and are seen to be consistent with the relative orbital energies, dxy > dx2–y2 > dz2 > dxz yz. The crystal-field parameters obtained are shown to agree closely with those for CaCu(AcO)4,6H2O when allowance is made for the different Cu–O distances involved.
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