Abstract
Tetrahedral complexes with an excited state consisting of two closely lying triplet states are considered. The full interaction Hamiltonian, including ligand field, Jahn-Teller, pseudo-Jahn-Teller, and spin-orbit interactions is constructed. The emission-band shape is numerically calculated within the semiclassical approach using Monte Carlo integration. The results of this numerical analysis are applied to the ${\mathrm{PbWO}}_{4}$ system. Comparison with experimentally obtained spectra shows that this theory explains the observed triple-peak structure.
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