Abstract
By single crystal X-ray diffraction, the structure of a new compound based on octahedral mixed-ligand anionic cluster complexes of rhenium and cadmium(II) cations is determined: K0.4Cs0.6{Cd(H2O)2Re6S8(CN)4(OH)(H2O)}•8H2O (1). The compound has a framework structure with a pts (platinum sulfide) topology. The cluster anions are additionally chained together by strong OH⋯H2O hydrogen bonds between the terminal ligands of neighboring clusters; the O⋯O distance is 2.464 A.
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