Abstract
Aqueous solutions of tert-butyl alcohol (2-methyl-2-propanol) were investigated using sound velocity and positron annihilation methods. The results are interpreted in terms of changing structure of solution, especially formation of clathrate-like hydrates. The annihilation method was found to be applicable for investigating the structure of aqueous solutions of non-electrolytes. Resolution of annihilation spectrum into three components (instead of two) yield non-physical parameters, suggesting that the short-lived mechanisms of annihilation of positrons are too close to be separated.
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