Abstract
We employed nanometer-scale spatially resolved electron energy loss spectroscopy to monitor the degree and localization of electronic passivation of graphene surfaces by using the π-plasmon as an indicator of sp2-bonding. Upon hydrogenation, the π-plasmon does not vanish, and a new feature at 7 eV occurs in the spectra. This behavior conforms to the theoretical electron energy loss spectra derived from density functional calculations for partial hydrogenation, with benzene rings assuming a corrugated structure. The spatial distribution of the spectral features and atomic resolution Z-contrast images indicate absence of any long-range ordering in the hydrogenated areas.
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