Abstract
The bis(cyclopropylammonium)dihydrogenodiphosphate monohydrate is a new diphosphate associated with the organic molecule C 3H 5NH 2. We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C 3H 5NH 3) 2H 2P 2O 7.H 2O is orthorhombic (S.G. : P2 12 12 1), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P 2O 7 groups and H 2O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.
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