Structure, characterization and near-infrared emission of a novel 6-connected uninodal 3D network of Nd(III) containing 2,5-thiophenedicarboxylate anion

Abstract

Abstract The novel coordination polymer with the formula {[Nd2(2,5-tdc)3(dmf)2(H2O)2].dmf.H2O}n (2,5-tdc2 − = 2,5-thiophedicarboxylate anion and dmf = dimethylformamide) has been synthesized and characterized by thermal analysis (TG/DTA), vibrational spectroscopy (FTIR) and single crystal X-ray diffraction analysis (XRD). Structure analysis reveals that Nd(III) ions show dicapped trigonal prism coordination geometry. The 2,5-tdc2 − ligands connect four Nd(III) centers, adopting (κ1 – κ1) – (κ1 – κ1) – μ4 coordination mode, generating an interesting 6-connected uninodal 3D network. Photophysical properties were studied using diffuse reflectance spectroscopy (DR) and excitation/emission spectra. The photoluminescence data show the near infrared emission (NIR) with the characteristic 4F3/2 → 4IJ (J = 9/2, 11/2 and 13/2) transitions of Nd(III) ion, indicating that 2,5-tdc2 − is able to act as a sensitizer for emission in NIR region.