Terbium(III) and dysprosium(III) 8-connected 3D networks containing 2,5-thiophenedicarboxylate anion: Crystal structures and photoluminescence studies

Abstract

Two novel coordination polymers with the formula {[Ln2(2,5-tdc)3(dmso)2]·H2O}n (Ln=Tb(III) for (1) and Dy(III) for (2)), (2,5-tdc2−=2,5-thiophenedicarboxylate and dmso=dimethylsulfoxide) have been synthesized by the diffusion method and characterized by thermal analysis, vibrational spectroscopy and single crystal X-ray diffraction analysis. Structure analysis reveals that 2,5-tdc2− play a versatile role toward different lanthanide ions to form three-dimensional metal-organic frameworks (MOFs) in which the lanthanides ions are heptacoordinated. Photophysical properties were studied using excitation and emission spectra, where the photoluminescence data show the high emission intensity of the characteristic transitions 5D4→7FJ (J=6, 5, 4 and 3) for (1) and 4F9/2→6HJ (J=15/2, 13/2 and 11/2) for (2), indicating that 2,5-tdc2− is a good sensitizer.