Abstract

The phase composition and the structure of the solidified mattes of the autogenous smelting of copper–zinc concentrates containing 49.8 and 61.0% Cu in Vanyukov’s furnace are studied. The forms of the main elements (Cu, Ni, Fe, S, O) and the accompanying impurities (Zn, Pb, As, Sb, Co, Sn, Au, Ag) in the rich matte are determined. The phase-transformation temperatures in cooling of the mattes in an inert or oxidizing gas atmosphere are found.

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