Abstract
The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [RuIV(bdpm)(pic)2(mCPBA)]+ (H2bdpm = [2,2'-bipyridine]-6,6'-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C-H bond activation and O-atom transfer reactions.
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