Abstract
The new compound (CH3NH3)3Tl2Cl9 was synthesized and fully characterized. X-ray photoelectron spectroscopy and Raman spectroscopy are consistent with the crystal structure solved by single-crystal X-ray diffraction. This compound is a semiconductor with a measured band gap of Eg = 2.91 eV. It is the first thallium-based hybrid perovskite and shows remarkably high stability to ambient conditions.
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