Abstract
The X-ray diffraction, electron microscopy and electron diffraction studies of the structure and morphology of poly(2,3-dichlorobutadiene) confirmed the polymorphic character of this polymer. The structure of polymerized samples or samples crystallized from solution is monoclinic. By annealing the original monoclinic sample at temperatures above 140°C or by crystallizing from the melt, the orthorhombic crystal modification is formed. The variety of morphological structures found in solution-crystallized samples depends on the quality of the solvent or solvent—non-solvent system used.
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