Abstract
In studies of a series of crystals of layered metal phosphate compounds by magic angle spinning (MAS) NMR spectroscopy, it has been found that there is a distinct correlation between the 31 P isotropic chemical shift value and the type of phosphate group. The isotropic 31 P chemical shifts of (H 2 PO 4 ) - , (HPO 4 ) 2- and (PO 4 ) 3- groups appear around δ -10, -20 and -30, respectively. These assignments were made unambiguously by measuring the 31 P MAS NMR spectra with and without 1 H high-power decoupling together with the cross-polarization transfer technique between 1 H and 31 P nuclei (CP MAS spectra).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
