Abstract
The structure of the title compound has been determined by single-crystal X-ray diffractometry using Patterson and Fourier techniques. Crystals are orthorhombic, space group P212121, with Z= 12 in a unit cell of dimensions a= 24.336(4), b= 33.192(4), and c= 9.408(2)A. The structure has been solved by constructing a pseudo-cell related to the unit cell such that a′=a, b′=b//3, and c′=c, and re-indexing the reflections such thaf h′=h, k′=k//3 and I′=I, and refined by block-diagonal least-squares methods to R 0.081 for 1 942 re-indexed reflections. The tin atom is co-ordinated in a distorted octahedral fashion by two chlorine atoms occupying cis positions [Sn–Cl 2.361(5)A, Cl–Sn–Cl 99.0(2)°] and by two N-benzoyl-N-phenylhydroxylaminato-residues which chelate the tin nearly symmetrically [Sn–O 2.04(2), 2.1 l(2)A].
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