Abstract
The crystal structure, cryogenic magnetic properties, and magnetocaloric performance of double perovskite Eu2NiMnO6 (ENMO), Gd2NiMnO6 (GNMO), and Tb2NiMnO6 (TNMO) ceramic powder samples synthesized by solid-state method have been investigated. X-ray diffraction structural investigation reveal that all compounds crystallize in the monoclinic structure with a P21/n space group. A ferromagnetic to paramagnetic (FM-PM) second-order phase transition occurred in ENMO, GNMO, and TNMO at 143, 130, and 112 K, respectively. Maximum magnetic entropy changes and relative cooling power with a 5 T applied magnetic field are determined to be 3.2, 3.8, 3.5 J/kgK and 150, 182, 176 J/kg for the investigated samples, respectively. The change in structural, magnetic, and magnetocaloric effect attributed to the superexchange mechanism of Ni2+–O–Mn3+ and Ni2+–O–Mn4+. The various atomic sizes of Eu, Gd, and Tb affect the ratio of Mn4+/Mn3+, which is responsible for the considerable change in properties of double perovskite.
Highlights
The crystal structure, cryogenic magnetic properties, and magnetocaloric performance of double perovskite Eu2NiMnO6 (ENMO), Gd2NiMnO6 (GNMO), and Tb2NiMnO6 (TNMO) ceramic powder samples synthesized by solid-state method have been investigated
The magnetocaloric effect (MCE) is a phenomenon of the coupling effect between the magnetic moment alignment with application and removal of magnetic field, which is strongly associated with the magnetic phase transition
Jia et al studied the magnetocaloric effect in L n2(Ni/Co)MnO6 and discovered that these Double perovskites (DPs) exhibit multiple magnetic phase transitions, and Tc decreases with decreasing ionic radii of rare earth elements[20]
Summary
The crystal structure, cryogenic magnetic properties, and magnetocaloric performance of double perovskite Eu2NiMnO6 (ENMO), Gd2NiMnO6 (GNMO), and Tb2NiMnO6 (TNMO) ceramic powder samples synthesized by solid-state method have been investigated. We studied the influence of rare earth element ionic size in R 2NiMnO6 (R = Eu, Gd, Tb) double perovskite on structural, magnetic, and magnetocaloric properties at cryogenic temperatures.
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