Abstract

Dibutyltin and dioctyltin esters of ferrocenecarboxylic acid and dibutyltin ester of 1,1′-ferrocenedicarboxylic acid have been synthesized and characterized by IR and NMR ( 1H, 13C, 119Sn) spectral data. Spectroscopic data suggest that the esters of ferrocenecarboxylic acid adopt an oxygen-bridge dimer structure mode. The structure features four anisobidentate bridging carboxylate ligands. The ester of 1,1′-ferrocenedicarboxylic acid is five-coordinate monomer in solution.

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