Abstract
Primary amines react with a variety of cationic and neutral iron isocyanide complexes to yield structural and rotational diaminocarbene isomers characterized by variable temperature 1H and 13C NMR spectra. Structural isomers result from the conversion of amines to isocyanide ligands via the base-catalyzed nucleophilic attack of initially formed diaminocarbenes on cis isocyanides substituents, the effect on isomer populations is often marked. Factors influencing structural and rotational isomeric preferences are discussed.
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