Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K S Mok,H W Tong,C K Poon

doi:10.1039/dt9720001701

Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K S Mok, H W Tong + Show 1 more

https://doi.org/10.1039/dt9720001701

Copy DOI

Journal: J. Chem. Soc., Dalton Trans.	Publication Date: Jan 1, 1972
Citations: 6

#Central Cobalt #Amine Complexes + Show 8 more

Abstract
Full-Text
Similar Papers

Abstract

The prepration and characterization of trans-[Co(NH3)4(NCS)Cl]+ cation is described. The kinetics of the aquation and base hydrolysis of this complex cation and those of trans-[Co(cyclam)(NCS)Cl]+ have been studied over a range of temperature. These results are discussed in terms of the influence of nephelaxetic effects of these amine ligands on the central cobalt(III) ion.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Similar Papers

Paper Title

Journal

Date

Author

View more papers

More From: J. Chem. Soc., Dalton Trans.

Paper Title

Journal

Date

Author

View more papers

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.