Abstract

Abstract In order to discuss the effect of dynamic modulation caused by hydrogen-bonded system on the conduction property, two Ni(dmit)2 salts were prepared. In morpholinium salts a remarkable structural modulation was observed on the hydrogen-bonded Ni(dmit)2 molecules. In the crystal of hydrated lithium salts, the hydrogen-bonded cation system is incorporated in a cylindrical channel constructed by corrugatedly stacked Ni(dmit)2 columns, and a distinct hysteresis was observed on the temperature dependence of conductivity.

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