Abstract

Sol-gel auto combustion method was adopted for the synthesis of Bi1-xCaxFeO3 (x = 0.00, 0.05, 0.1, 0.15, 0.2 and 0.25) multiferroic nanoparticles and their structural and electric properties were investigated. The two peaks at (012) and (110) planes at diffracting angles (2θ) of 31.9° and 32.1° in the XRD pattern indicates their rhombohedral structure with the R3c space group. The cole-cole plot in the 10 Hz–1 MHz frequency range shows the increasing semicircles shifting towards higher frequency, indicating increasing grain and grain boundaries.

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