Abstract
Reference linearized hypernetted chain (RLHNC) equations for mixtures of dipolar molecules with a spherically symmetrical reference potential are presented and solved for binary mixtures of hard spheres. The dependence of the dielectric constant, the dipolar contribution to the internal energy, and the orientation-dependent components of the pair distribution functions on composition, molecular sizes, and dipole moments is studied. The RLHNC approximation results for the composition dependence of the dipolar internal energy are found to be in excellent agreement with Monte Carlo simulation data. The RLHNC theory is found to overestimate the dielectric constant at high dipolar strengths. Values of the dielectric constant in much better agreement with Monte Carlo data are obtained by using the perturbation theory.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
