Abstract
Abstract Polarographic reduction behaviors of fac-[Cr(AA)3] complexes, where AA is an L-α-amino acidato ligand, have been studied in Me2SO. These complexes showed two reduction waves at mercury electrode and the first corresponded to Cr(III) → Cr(II). This reduction potential was found to be more positive for the (+)546-isomer than for the corresponding (−)546-isomer in the presence of Et4N+.
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