Abstract
Abstract Stereoselective synthesis of 2,2‐disubstituted 1‐fluoro‐alkenes: (E)‐[[fluoro(2‐phenylcyclohexylidene)‐methyl]sulfonyl]benzene and (Z)‐[2‐(fluoromethylene)‐cyclohexyl]benzene product: (E)‐[[Fluoro(2‐phenylcyclohexylidene)methyl]sulfonyl]benzene (1) reactant: diethyl chlorophosphate (24.8 g, 0.14 mol) intermediate: (E)‐Tributyl[fluoro(2‐phenylcyclohexylidene)methyl]stannane (2) product: (Z)‐[2‐(Fluoromethylene)cyclohexyl]benzene (3)
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