Abstract
A novel type of C 2-symmetric-chiral ligand, based on a cubane-like photodimer 1 of methyl 2-naphthoate, is reported in this work. Crystal analysis reveals that the methyl carboxylate functionality is in an anti-head-to-head conformation and 1 is highly rigid. The optically pure enantiomers of 1 can be obtained simply by HPLC resolution.
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