Abstract
High resolution 1H-NMR spectra of 2-hydroxyethyl methacrylate (HEMA)-styrene (S) copolymers prepared at low conversion by free radical copolymerization in N,N-dimethylformamide (DMF) solution at 50°C, have been analyzed in terms of sequence distribution and stereoregularity. The Bootstrap effect for the HEMA/S/DMF system was confirmed by comparison of the data obtained with those previously reported for the HEMA/S/bulk system. Reactivity ratios, statistical parameters, and the coisotacticity parameter σHS = 0.40, estimated at low conversion, were used to describe the observed experimental changes in copolymer composition and triad fraction intensities over a wide range of conversions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
