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https://doi.org/10.1021/acs.orglett.4c04663
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Cite Journal: Organic letters |  Publication Date: Jan 9, 2025 |
A Brønsted acid-catalyzed enantioselective synthesis of (Z)-1,3-butadienyl-2-carbinols is developed. By employing a chiral phosphoric acid as the catalyst, a variety of 1,3-butadienyl-2-carbinols were obtained in good yields with excellent Z-selectivities and enantiopurities from α-alkyl-substituted homoallenyl boronates.
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