Abstract

We report surprising steady oscillations in aggregation-fragmentation processes. Oscillating solutions are observed for the class of aggregation kernels K_{i,j}=i^{ν}j^{μ}+j^{ν}i^{μ} homogeneous in masses i and j of merging clusters and fragmentation kernels, F_{ij}=λK_{ij}, with parameter λ quantifying the intensity of the disruptive impacts. We assume a complete decomposition (shattering) of colliding partners into monomers. We show that an assumption of a steady-state distribution of cluster sizes, compatible with governing equations, yields a power law with an exponential cutoff. This prediction agrees with simulation results when θ≡ν-μ<1. For θ=ν-μ>1, however, the densities exhibit an oscillatory behavior. While these oscillations decay for not very small λ, they become steady if θ is close to 2 and λ is very small. Simulation results lead to a conjecture that for θ<1 the system has a stable fixed point, corresponding to the steady-state density distribution, while for any θ>1 there exists a critical value λ_{c}, such that for λ<λ_{c}, the system has an attracting limit cycle. This is rather striking for a closed system of Smoluchowski-like equations, lacking any sinks and sources of mass.

Highlights

  • Numerous phenomena in nature involve dual processes of aggregation and fragmentation [1,2]

  • We have studied numerically and analytically a class of aggregation-fragmentation models with a conservation of mass, which lack source and sinks of particles

  • It is described by the infinite set of Smoluchowski-like equations with the homogeneous aggregation and fragmentation kernels which respectively read Ki,j = iν j μ + j ν iμ and Fi,j = λKi,j, where the parameter λ quantifies the intensity of fragmentation

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Summary

INTRODUCTION

Numerous phenomena in nature involve dual processes of aggregation and fragmentation [1,2]. These processes take place on vastly different length and time scales. A reversible polymerization in solutions and coagulation of colloidal particles are the classical examples of such processes occurring on the molecular scales; another peculiar example is aggregation of prions causing the Alzheimer-like diseases [3]. On the larger scales—in atmospheric processes, small airborne particles coalesce into smog droplets [4]. Aggregation and fragmentation processes occur in networks of different nature, including economic networks [7] and internet communities [1,8]; here forums of users nucleate, merge, and split. The distribution of particles size in planetary rings is determined by a steady balance achieved between two opposite processes, viz. aggregation and breakage of the particles in the rings [10,11,12,13,14]

Aggregation
Aggregation with fragmentation
NUMERICAL RESULTS
Steady-state size distribution
Oscillating solutions
THEORETICAL ANALYSIS
Asymptotic analysis of a steady-state cluster size distribution
Qualitative analysis
Concentration oscillations in thermodynamically closed systems
CONCLUSIONS
Full Text
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