Abstract

By using scaling analysis it is shown that the presence of a steady-state particle distribution is compatible with standard mechanisms of crystallite sintering in catalysts if fragmentation kernels are added. Analytical solutions are found when aggregation and fragmentation kernels are homogeneous, but the results can be extended to kernels with different properties. This provides a theoretical justification for the use of steady-state dispersions during kinetic analysis of sintering using the generalized power law equation.

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