Status of copper accumulation in agricultural soils across China (1985-2016).

Abstract

The first national-scale assessment of Cu contamination of agricultural soils covering 1731 sites in China was performed based on 1837 published papers. The temporal and spatial variations from 1985 to 2016 in the Cu concentrations and the ecological and health risks associated with Cu exposure were analyzed. Approximately, 21.02% of the sampling sites revealed Cu concentrations that exceeded the screening value (50.00mg/kg; GB15618-2018). The Cu concentrations differed among five geographical regions in the decreasing order of South China>West China>East China>Northeast China>North China. Notably, concentration of Cu in agricultural soils have begun to diminish since 2011 due to reduced heavy metal inputs. Cu mainly originated from anthropogenic activities such as mining and agricultural activities. Linear correlations were observed between the amounts of fungicides and fertilizers applied and the Cu concentrations in the soils, which suggested that the application of fungicides and fertilizers is an important contributor to the accumulation of Cu in soils. Additionally, the geoaccumulation index (Igeo) and ecological risk index (Efi) values implied that pollution and ecological risk resulting from soil Cu concentration were in low levels. The hazard index (HI) values were higher for children than for adults. Therefore, children should be prioritized for protection from heavy metal pollution. Overall, this study details the status of Cu contamination of agricultural soils in China, and thus provides insights for policymakers regarding the preventive measures.