Abstract
The equation of state of the A a D a type hydrogen bonding fluid is studied by the statistical mechanics theory, the influences of hydrogen bonds on the volume of the system and the equation of state are presented. Moreover, the number density fluctuations of the molecules and hydrogen bonds, and the spatial correlation property between them are investigated. Furthermore, an equation describing relation between the number density correlation function of “molecules-hydrogen bonds” and that of molecules and hydrogen bonds is derived. At last, by taking the van der Waals hydrogen bonding fluid as an example, we considered
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