Abstract
The influence of chlorine atoms on the ionization and solvation processes for 2,6- and 3,5-chloro disubstituted benzoic derivatives was studied from the statistical viewpoint. This study was carried out by comparing the enthalpy values of these processes with those of the corresponding monosubstituted chloro derivatives in water-DMSO mixtures over the mole fraction range 0–0.8. For this purpose, a monoparametric regression analysis was used. In this analysis, total standard deviation, slope and intercept standard deviations, correlation coefficient and the Student t-test of the enthalpy values were taken into account. The additive principle for both compounds and steric effect for the 2,6-dichloro derivative were also studied.
Published Version
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