Abstract

The potential energy surfaces for the ground and low-lying excited states of the H − 3 system are calculated by means of the diatomics-in-molecule (DIM) method. State-to-state reaction probabilities for rearrangement in H − + H 2, D 2 collisions are calculated by the S matrix Kohn variational method in the discrete variable representation for the collinear configuration, and the results for H − + D 2 collisions are compared with recent experimental data.

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