Starch-g-Acrylic Acid/Magnetic Nanochitin Self-Healing Ferrogels as Flexible Soft Strain Sensors.

Abstract

Mechanically robust ferrogels with high self-healing ability might change the design of soft materials used in strain sensing. Herein, a robust, stretchable, magneto-responsive, notch insensitive, ionic conductive nanochitin ferrogel was fabricated with both autonomous self-healing and needed resilience for strain sensing application without the need for additional irreversible static chemical crosslinks. For this purpose, ferric (III) chloride hexahydrate and ferrous (II) chloride as the iron source were initially co-precipitated to create magnetic nanochitin and the co-precipitation was confirmed by FTIR and microscopic images. After that, the ferrogels were fabricated by graft copolymerisation of acrylic acid-g-starch with a monomer/starch weight ratio of 1.5. Ammonium persulfate and magnetic nanochitin were employed as the initiator and crosslinking/nano-reinforcing agents, respectively. The ensuing magnetic nanochitin ferrogel provided not only the ability to measure strain in real-time under external magnetic actuation but also the ability to heal itself without any external stimulus. The ferrogel may also be used as a stylus for a touch-screen device. Based on our findings, our research has promising implications for the rational design of multifunctional hydrogels, which might be used in applications such as flexible and soft strain sensors, health monitoring, and soft robotics.