Abstract
1,3-Bis(boryloxy)tetraalkyldistannoxanes, ▪, R = Me, Bu; G = CMe 2CH 2CHMe—, —CMe 2 —CMe 2 — and —CHMe—CH 2 — have been prepared from dialkyltin oxide and pyroborate, or directly from dialkyltin oxide, boric acid and glycol. A dimeric structure for these compounds is proposed on the basis of molecular weight, IR and PMR studies. The reactivity of the SnOB bond towards PhNCO and Me 3SiCl has been demonstrated.
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