Abstract

Two diastereomers of 1,2,3,4,5-pentachlorocyclohexane and two diastereomers of tetrachloromonomethoxycyclohexane were synthesized stepwise from diastereomers of 3,4,5-trichlorocyclohexene, which had been derived from the dl-(36/45)-, dl-(34/56)- and (346/5)-isomers of 3,4,5,6-tetrachlorocyclohexenen (α-, β- and γ-BTC, respectively) by selective reduction with LiAlH4. The configurations of all the products and intermediary trichlorocyclohexene isomers were determined by PMR studies.

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