Abstract
Combustion iron (Fe) in aerosols is one of the sources of dissolved Fe in the surface ocean. The iron isotope ratio (δ56Fe) is an important tool for source apportionment of Fe because combustion Fe emitted by evaporation possibly yields lower δ56Fe values than natural materials. However, there are insufficient data of δ56Fe for combustion Fe. Hence, δ56Fe values of Fe emitted from a steel plant were investigated, and the representative δ56Fe value of combustion Fe was discussed. The presence of a large number of submicron spherical Fe oxide particles suggested that the particles were emitted by high-temperature evaporation. Fine particles yielded much lower δ56Fe (as low as −3.53‰) than original materials, indicating that Fe isotope fractionation occurred during evaporation. Based on this study and our previous data, we suggest −3.9‰ to −4.7‰ as the representative δ56Fe range of combustion Fe. Mass balance calculations using this range suggest that the contribution of combustion Fe is approximately 57–83%...
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