Abstract
Improved experimental technique has been used to stabilized hydrogen and deuterium atoms in solid Ar and Ne matrices. It is found that H and D atoms are stabilized in these matrices at two nonequivalent trapping sites. For H and D atoms in solid argon, the narrowest experimentally recorded EPR spectral lines having a width ΔH = 55 (15) mG have been observed during matrix isolation of particles. The isotope effect has been detected in the matrix shifts of hyperfine structure constants of stabilized atoms.
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