STABILITY OF COBALT AND NICKEL COMPLEXES OF SUCCINIC AND MALEIC IONS STUDIED BY POTENTIOMETRIC TITRATION, UV-VIS SPECTROPHOTOMETRY AND QUANTUM CHEMICAL CALCULATIONS

Abstract

In this study, composition and stability of coordination compounds of nickel (II) and cobalt (II) ions with succinate anion (L2-) and maleic anion (Y2-) in aqueous ethanol solutions with the molar concentration of ethanol ranging from 0.0 – 0.3 were studied by UV – Vis spectrophotometry at ionic strength of 0.1 maintained with sodium perchlorate. The result showed that, the formation of mono-ligand complexes of Ni2+ and Co2+ ions with succinate and maleic anions become stronger when the volume of ethanol rises. This may be due mainly to a change in the solvate state of the ligand with increasing ethanol concentration in the solvent. In all surveyed solvents, Co2+ forms less stable complexes than Ni2+ ion corresponding to the Irving-Williams series established for aqueous solutions. Obtained results were compared with literature data for akin compounds. The effect of solvent composition change on the geometry, charge, total electron and free Gibbs energies was studied using the DFT and MP2 levels of theory by using the Polarizable Continuum Model (PCM). The results obtained in this article by UV – Vis spectrophotometry and theoretical calculations were analyzed together with the potentiometric titration results obtained by us earlier for these complexes. The results of theoretical calculations are in good agreement with experimental data.