Abstract

First- and second-order perturbation calculations of the energy of interaction were carried out for triplets of atoms or ions in rare-gas solids, since alkali halide ions are isoelectronic, for three-body exchange interactions with two atoms or ions as nearest neighbors of the third, to determine the three- body-interaction stabilizing effect on alkali halide crystals. A Gaussian effective-electron charge configuration is used for the ions of the alkaii halide crystals. Results are given for cesium chloride, sodium chloride, cesium iodide, and rubidium chloride. (R.E.U.)

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