Abstract

Since Onsager's seminal work, hard rods have been taken as a prototype of nematic liquid crystals, characterized by uniaxial order and a uniform director field as a ground state. Here, using Onsager theory to calculate the free energy in the presence of arbitrary deformations, we find that hard rod nematics have an intrinsic tendency to twist around their ordering axis (double twist), driven by a mechanism in which the orientational fluctuations of particles play a key role. The anisotropic hard core potential used here is arguably the simplest form of interaction able to originate spontaneous breaking of mirror symmetry in a 3D fluid. Our results are discussed in relation to the recent discovery of a double twisted ground state in cylindrically confined lyotropic chromonic liquid crystals.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.