Spontaneous and Continuous Actuators Driven by Fluctuations in Ambient Humidity for Energy-Harvesting Applications.

Abstract

Self-oscillating soft actuators that enable spontaneous and continuous motion under an external stimulus with no human intervention have attracted extensive attention due to the great value of the realization of more sustainable and low-power-consumption actuators. However, the achievement of such actuators that collect chemical energy from the fluctuations in ambient humidity is still a great challenge. Here, an actuator film based on spiropyran@agarose (SP@AG) that can spontaneously and continuously collect chemical energy from the fluctuations in ambient humidity is developed. It is noteworthy that the SP@AG film has excellent self-oscillation behavior and a high oscillation amplitude (184°) under the size (40 × 8 mm) or load of 116 mg (about 5.2 times of the film weight). Moreover, on the basis of the self-oscillating motion, an energy conversion device is constructed by integrating the soft actuator with a piezoelectric PVDF film, which can spontaneously and continuously generate an output voltage of about 30 mV. Finally, a proof of concept for an "intelligent light-controllable window" that can open under humidity stimulus and change color under light is proposed herein. Overall, the self-oscillating actuator driven by fluctuations in ambient humidity shows immense potential in response to the atmospheric humidity of day-night rhythm and humid-energy-harvesting devices.