Abstract
Abstract High resolution x-ray diffraction, strain gauge and Raman spectroscopy measurements of Ca2FeAlO5 as a function of temperature is reported, which provides the evidence of negative thermal expansion (NTE) and strong spin-lattice coupling in this compound. The unit cell showed a decrease in volume with increase in temperature with a distinct jump around 70 °C which corroborates with the magnetic ordering temperature and showed a contraction under magnetic field. The Raman spectra showed variation under magnetic field supporting spin-lattice coupling at room temperature. Most importantly, the NTE (β ≅ − 6.41 × 10−5 °C−1) is observed from room temperature up to ∼70 °C making it very attractive for applications.
Published Version
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