Abstract
In this report we present a UV-Vis spectroscopic study of the pH dependent optical properties of 4,4'-azobenzene dicarboxylic acid in aqueous solution. A combination of chemical (acid-base) and light stimuli is combined to demonstrate that the system undergoes two types of optical switching cycles. At neutral pH the azobenzene undergoes photo-induced cis-trans isomerisation. Upon pH reduction the UV-Vis spectra show changes consistent with aggregation of the azobenzene photo-switch. The photo-responsive behaviour is dependent on the pH and conformation of the azobenzene. The optical properties of the system are dependent on the mode of pH reduction and the isomeric cis/trans composition of the photo-switch, showing hierarchical control of self-assembly.
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